工业固体废弃物中硫化钠的资源化利用研究进展
贵州轻工职业技术学院, 贵州贵阳 561100
| 摘 要： | 硫化钠，俗称硫化碱，化学式为Na2S，是一种白色或淡黄色结晶性粉末，具有强烈的刺激性气味。硫化钠具有多种物理和化学性质，如还原性、氧化性、吸附性等，因此在许多领域得到广泛应用。在传统工业中，硫化钠通过提高造纸、印染和橡胶制品的生产效率，同时减少废物的产生。环保领域内，硫化钠有效处理含重金属废水，实现资源回收，并在烟气脱硫中发挥作用，减少污染物排放。在电池制造中，硫化钠促进了钠硫电池等新能源技术的发展，提高了电池回收利用的可能性。农业上，硫化钠用于土壤改良和重金属固定，提升了土壤质量，减少了农业固废。医药领域也利用硫化钠进行药物合成和生物检测，推动了固废的资源化利用。近年来，随着经济技术的快速发展，硫化钠产业也取得了显著成果。随着对环保的重视，硫化钠在固废利用方面的研究与发展将更加注重环境保护和资源循环利用，推动实现工业生产的绿色化和可持续发展。本文对硫化钠的主要应用领域进行综述，包括传统工业、新能源、环保、农业、医药等方面，旨在为中国硫化钠产业的发展提供参考。 |
| 关 键 词： | 硫化钠; 资源利用; 固体废物; 电池 |
| DOI： | 10.57237/j.res.2024.03.003 |
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收稿日期: 2024-08-05
接受日期: 2024-08-28
在线出版日期: 2024-09-09
Research Progress on the Resource Utilization of Sodium Sulfide in Industrial Solid Waste
Guizhou Light Industry Vocational and Technical College, Guiyang 561100, China
| Abstract: | Sodium sulfide, commonly known as sodium sulfide, with the chemical formula Na2S, is a white or pale yellow crystalline powder characterized by a strong pungent odor. Sodium sulfide possesses a variety of physical and chemical properties such as reducibility, oxidizability, and adsorbability, which have led to its widespread application in numerous fields. In traditional industries, sodium sulfide enhances the production efficiency of papermaking, dyeing, and rubber products while reducing waste generation. Within the environmental protection sector, sodium sulfide effectively treats heavy metal-containing wastewater, facilitating resource recovery and playing a role in flue gas desulfurization to diminish pollutant emissions. In battery manufacturing, sodium sulfide has promoted the development of new energy technologies such as sodium-sulfur batteries, improving the potential for battery recycling and reuse. In agriculture, sodium sulfide is utilized for soil improvement and heavy metal immobilization, enhancing soil quality and reducing agricultural solid waste. Additionally, in the pharmaceutical field, sodium sulfide is employed in drug synthesis and biological detection, driving the resource utilization of solid waste. In recent years, with the rapid development of economic technology, the sodium sulfide industry has also achieved significant progress. With the increasing emphasis on environmental protection, research and development of sodium sulfide in solid waste utilization will focus more on environmental protection and resource recycling, promoting the greenization and sustainable development of industrial production. This paper provides a review of the primary application areas of sodium sulfide, including traditional industries, new energy, environmental protection, agriculture, and pharmaceuticals, aiming to offer a reference for the development of China's sodium sulfide industry. |
| Keywords: | Sodium Sulfide; Resource Utilization; Solid Waste; Battery |
基金
| 1. | 贵州轻工职业技术学院2024院级项目 (No. 24QY40) |
参考文献
| [1] | 高军, 沈伟, 亓虎, 等.含硫化钠废水制备无水硫化钠工艺研究 [J]. 当代化工研究, 2023, (11): 157-159. |
| [2] | 张宏, 李望, 赵和平, 等.以废气中的硫化氢开发含硫化学品的研究进展 [J]. 化工进展, 2017, 36(10): 3832-3849. |
| [3] | 刘华彦, 卢晗锋, 陈银飞.氢气还原法制硫化钠低温高活性催化剂研究 [J]. 化学反应工程与工艺, 2004, (04): 376-379. |
| [4] | 李伟达, 袁爱武, 吴桂荣.柠檬酸盐-硫化钠法脱硫制硫磺工艺的工业应用 [J]. 硫酸工业, 2014, (05): 14-16. |
| [5] | 彭宇行, 贺建业, 黄光琳. 金属钠—硫磺法合成聚苯硫醚 [J]. 化学研究与应用, 1990, (01): 44-50. |
| [6] | 张喆秋, 袁露成, 黄林青, 等. 砷、锑、铋在铜冶炼过程中的分布及其在冶炼副产物中的回收综述 [J]. 有色金属科学与工程, 2019, 10(01): 13-19+27. |
| [7] | 王德秋, 董群, 邹丹, 等. 有机预硫化剂的合成 [J]. 化学工业与工程, 2008, (04): 302-305. |
| [8] | 李可鸿. 煤还原法硫化碱制黄片碱 [J]. 新疆化工 1993, (1): 45-46. |
| [9] | 刘振冲, 杜昭, 马海彬. 硫化氢干法脱除技术及硫磺回收研究进展 [J]. 应用化工, 2023, 52(03): 911-916. |
| [10] | 荆小兵. 硫酸钡副产硫化碱蒸发器阻垢技术的应用研究 [J]. 无机盐工业, 2012, 44(01): 46-48. |
| [11] | 尚方毓, 吕红琴, 胡昉. 硫酸钡生产中的节能技术与应用 [J]. 无机盐工业, 2010, 42(03): 40-42+50. |
| [12] | 韩海霞, 陈英军. 硫酸钡废水的综合治理 [J]. 无机盐工业, 2005, (04): 36-37. |
| [13] | 朱宗伟, 李兵云, 李海龙. 竹龄对竹材化学成分及制浆造纸性能的影响 [J]. 中国造纸, 2023, 42(04): 8-13. |
| [14] | 王长建, 朱宏伟, 唐珲军, 等. 化学机械浆高浓废水经济性处理工艺 [J]. 中国造纸, 2023, 42(07): 165-168. |
| [15] | 王键. 棉秆制浆漂白新工艺及其机理的研究 [D]. 华南理工大学, 2006. |
| [16] | 李许生. 速生桉硫酸盐法蒸煮黑液预处理技术及其脱木素动力学研究 [D]. 广西大学, 2005. |
| [17] | 薛国新, 郑建文, 洪启清. 硫化钠预处理大叶相思树硫酸盐法深度脱木素蒸煮技术 [J]. 中国造纸学报, 1999, (S1): 10-14. |
| [18] | 郑明远. 硫化染料染色新型氧化还原体系的应用 [D]. 河北科技大学, 2014. |
| [19] | 游韶玮, 张欣, 毛祥, 等. 工业废碱处理及再利用研究进展 [J]. 湿法冶金, 2023, 42(02): 107-115. |
| [20] | 上海绒布厂染料回收小组. 印染废水中回收硫化、还原染料 [J]. 印染, 1980, (04): 31-34. |
| [21] | 宗立新. 硫化染料的环保卷染工艺 [J]. 染整技术, 2021, 43(10): 29-32. |
| [22] | Dong F C, Wang J H, Huang G, et al. Short-Flow and High-Efficiency Dyeing Process of Sulfur Black on Cotton Fabrics [J]. Advanced Materials Research, 2012, 441: 150-154. |
| [23] | 许世业, 徐海升, 李谦定, 等.有机硫化剂研究进展 [J]. 工业催化, 2014, 22(06): 416-421. |
| [24] | 王灿, 阮少阳, 尹超. 我国含硫硅烷偶联剂的生产与应用 [J]. 橡胶科技市场, 2011, 9(10): 8-12. |
| [25] | 李定龙, 姜晟. 重金属废水处理的方案比较研究 [J]. 工业安全与环保, 2005, (12): 18-19. |
| [26] | 杨龑, 陈进一, 王鑫, 等.硫化钠-重金属捕集剂组合处理酸性含镍废水 [J]. 电镀与环保, 2012, 32(05): 35-38. |
| [27] | 杨彤, 曹文海, 许耀生. 化学法处理重金属离子废水的改进 [J]. 电镀与精饰, 1999, (05): 38-40. |
| [28] | 郑亮.火电厂湿法烟气脱硫废水处理施工技术分析 [J]. 山西化工, 2023, 43(12): 210-212. |
| [29] | 韩卫博, 卞双, 汪涛, 等. 燃煤电厂脱硫废水及污泥中重金属污染物控制研究进展 [J]. 发电技术, 2020, 41(05): 497-509. |
| [30] | ZHAO W, ZHANG Z, XIN Y, et al. Na2S-modified biochar for Hg(II) removal from wastewater: A techno-economic assessment [J]. Fuel, 2024, 356: 129641. |
| [31] | 谢敏雄, 王晓东. 湿法炼金废水处理工艺的试验研究与流程选择 [J]. 黄金科学技术, 2011, 19(04): 62-64. |
| [32] | 童仕唐, 沈士德, DONDALW KIRK. 工业烟气脱硫同时制取硫化氢的初步研究 [J]. 武汉冶金科技大学学报, 1997, (02): 33-36. |
| [33] | 张辛铖. 含硫废气的创新型回收净化工艺 %J 化工管理 [J]. 2018, (22): 202-203. |
| [34] | WANG Y-X, YANG J, CHOU S-L, et al. Uniform yolk-shell iron sulfide-carbon nanospheres for superior sodium-iron sulfide batteries [J]. Nature Communications, 2015, 6. |
| [35] | BLOI L M, PAMPEL J, DöRFLER S, et al. Sodium sulfide cathodes superseding hard carbon pre-sodiation for the production and operation of sodium-sulfur batteries at room temperature [J]. 2020, 10(7): 1903245. |
| [36] | WEI P, YANG Y, LIU C-J, et al. Single-Monolayer Na2S Film on Metal Surfaces [J]. Advanced Functional Materials, 2024. |
| [37] | XIONG Z, NIE X, ZHANG B, et al. Na2S Cathodes enabling safety Room Temperature Sodium Sulfur Batteries [J]. 2024, 7(1): e202300503. |
| [38] | HU M, JU Z, BAI Z, et al. Revealing the Critical Factor in Metal Sulfide Anode Performance in Sodium-Ion Batteries: An Investigation of Polysulfide Shuttling Issues [J]. Small Methods, 2020, 4(1): e1900673. |
| [39] | LIU X, TAN Y, WANG W, et al. Ultrafine Sodium Sulfide Clusters Confined in Carbon Nano-polyhedrons as High-Efficiency Presodiation Reagents for Sodium-Ion Batteries [J]. ACS Applied Materials & Interfaces, 2021, 13. |
| [40] | ZHANG P Y, WU J B, JIANG X L, et al. First-Principles Investigation on Multi-Sodium Sulfide and Sodium Sulfide Clusters in Sodium-Sulfide Batteries [J]. Journal of the Electrochemical Society, 2023, 170(6): 060547. |
| [41] | WANG C, WANG H, HU X, et al. Frogspawn-coral-like hollow sodium sulfide nanostructured cathode for high-rate performance sodium-sulfur batteries [J]. 2019, 9(5): 1803251. |
| [42] | YE C, JIN H, SHAN J, et al. A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries [J]. Nature Communications, 2021, 12(1): 7195. |
| [43] | HU L, LI J, ZHANG Y, et al. Enhancing the Initial Coulombic Efficiency of Sodium-Ion Batteries via Highly Active Na2S as Presodiation Additive [J]. Small, 2023, 19: e2304793. |
| [44] | 刘琛, 侯占峰, 耿红娟, 等.浅议农药中间体二甲基硫醚的合成方法及工艺 [J]. 化工管理, 2020, (18): 14-15. |
| [45] | JAKSE R, RABER J, RABER M. The use of sodium sulfide to separate mercury from tissues preserved in Cialit and Merthiolate solutions [J]. Archives of oto-rhino-laryngology, 1987, 244(5): 259-261. |
| [46] | 吴川, 陈虹任, 陆永平, 等.铅冶炼场地土壤微生物群落结构与硫氧化菌作用 (英文) [J]. Journal of Central South University, 2024, 31(04): 1050-1063. |
| [47] | 李致同. 我国几种主要土壤中微生物硫循环代谢途径特征及硫循环功能微生物群落结构 [D]. 西南大学, 2023. |
| [48] | XIE W, YANG J, YAO R, et al. Impact Study of Impoundment of the Three Gorges Reservoir on Salt-Water Dynamics and Soil Salinity in the Yangtze River Estuary [J]. 2020, 36(1). |
| [49] | LIU W, WEI D, MI J, et al. Immobilization of Cu(II) and Zn(II) in simulated polluted soil using sulfurizing agent [J]. Chemical Engineering Journal, 2015, 277: 312-317. |
| [50] | XIAO L, ZHANG T, GUO M, et al. Comprehensive Detoxification of Heavy Lead-Contaminated Soil and Soil-Washing Wastewater: Efficient and Mild [J]. Water Air and Soil Pollution, 2023, 234(6): 337. |
| [51] | 李霞, 王晨, 刘利, 等. 磺胺类药物水环境行为及水生生物毒性研究进展 [J]. 环境工程技术学报, 2024, 14(02): 681-691. |
| [52] | 康舒, 周迎春, 张煜明, 等. 局部麻醉剂——对氨基苯甲酸的合成研究 [J]. 化学工程师, 2014, 28(03): 67-69. |
| [53] | Misak A, Kurakova L, Goffa E, et al. Sulfide (Na2S) and polysulfide (Na2S2) interacting with doxycycline produce/scavenge superoxide and hydroxyl radicals and induce/inhibit DNA cleavage [J]. Molecules, 2019, 24(6): 1148. |
| [54] | LIU L, WU B, YU P, et al. Sub-20 nm nontoxic aggregation-induced emission micellar fluorescent light-up probe for highly specific and sensitive mitochondrial imaging of hydrogen sulfide [J]. Polymer Chemistry, 2015, 6(29): 5185-5189. |
| [55] | BELTOWSKI J, WIORKOWSKI K. Role of Hydrogen Sulfide and Polysulfides in the Regulation of Lipolysis in the Adipose Tissue: Possible Implications for the Pathogenesis of Metabolic Syndrome [J]. International Journal of Molecular Sciences, 2022, 23(3): 1346. |
| [56] | 吴海祥, 吴维新, 岳涛, 等. 某铜冶炼渣浮选回收铜工艺试验研究 [J]. 矿冶工程, 2024, 44(01): 57-59+67. |
| [57] | 刘霄, 刘定富. 铁-碳微电解/改进硫化钠沉淀法处理综合电镀废水 [J]. 环保科技, 2021, 27(06): 15-17+32. |
| [58] | 徐芝芬. 制革废水多污染物生物强化协同去除机制研究 [D]. 陕西科技大学, 2023. |
| [59] | 李静, 陈张好, 周智明.高效液相色谱法测定染发产品中48种准用染料 [J]. 分析试验室, 2024, 43(07): 966-973. |
