含银的锗硫属化合物的合成发展研究
内蒙古师范大学, 化学与环境科学学院, 内蒙古呼和浩特 010022
| 摘 要： | 近年来，含锗的硫属化合物因其复杂的结构性质和潜在应用价值引起人们关注，并且在非线性光学、分子筛、离子交换等方面应用广泛。而族11元素Ag已被证明是成功的多功能元素经常被用于合成，因为它们本身具有丰富的配位方式和电热性能，除此之外还增强了亲金属相互作用，克服了阳离子金属中心之间的排斥力，更容易进入骨架形成具有独特拓扑结构的新型材料。这些材料的潜在应用超越了传统领域。本文综述了含过渡金属银的锗硫属化物化合物的合成方法和结构方面的研究进展；并总结过渡金属银和锗硫属化合物基本骨架中结构单元多种配位方式，不同含过渡金属银的锗硫属化物的合成方法，结构特点及其应用。以及碱金属、过渡金属配合物、有机胺等做结构导向剂时含银的锗硫属化合物的合成方法结构特点和性能。 |
| 关 键 词： | 过渡金属银; 锗硫属化合物; 晶体结构; 合成方法 |
| DOI： | 10.57237/j.mater.2023.01.002 |
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收稿日期: 2023-02-20
接受日期: 2023-03-17
在线出版日期: 2023-03-28
Progress in the Synthesis of Germanium Chalcogenides Containing Silver
College of Chemistry & Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China
| Abstract: | In recent years, germanium containing sulfur compounds have attracted much attention due to their complex structural properties and potential applications, and have been widely used in nonlinear optics, molecular sieve, ion exchange and so on. Group 11 elements Ag have been proved to be successful multifunctional elements often used for synthesis, because they have rich coordination modes and electrothermal properties. In addition, they also enhance the metalophilic interaction, overcome the repulsive force between cationic metal centers, and more easily enter the skeleton to form new materials with unique topological structures. The potential applications of these materials extend beyond traditional fields. The synthesis and structure of germanium chalcogenides containing transition metal silver are reviewed in this paper. Various coordination modes of structural units in the basic framework of transition metal silver and germanium sulfide compounds, synthesis methods, structural characteristics and applications of different germanium sulfide compounds containing transition metal silver are summarized. And the synthesis of germanium sulfide compounds containing silver when alkali metals, transition metal complexes, organic amines are used as structure guide agent. |
| Keywords: | Transition Metal Silver; Germanium Chalcogenide; Crystal Structure; Synthesis Method |
基金
| 1. | 内蒙古高校科研项目 (NJZZ22586) |
| 2. | 国家自然科学基金 (21461019、21771029、11811530631、21573034) |
| 3. | 中央高校基本研究基本基金 (DUT22LAB602) |
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