1. 石家庄学院, 化工学院, 河北石家庄 050000
2. 河北省农业环境保护监测总站, 河北石家庄 050000
| 摘 要: | 随着能源、信息、环保与生物科学与技术的飞速发展,悠久历史的材料-陶瓷,也获得了新的研究进展,即功能陶瓷的开发现世。功能陶瓷凭借独特的热、电、磁、声、光等物理特性和化学,生物以及适当的力学等特性,在相关的科学研究和工程项目应用中发挥了关键的作用。又因为光催化技术有反应条件温和,操作方便及没有二次污染等特点,所以被认为是二十一世纪最具有应用前景的环境治理技术,即可以有效解决化石能源枯竭和环境污染等问题。除此之外,光催化技术还具有能耗低的特点,还成为了开发新能源的必要技术。若将功能陶瓷和光催化技术两者结合在一起,那将会解决工业生产及生活中的很多问题。而功能陶瓷中具有光催化特性的材料现已被研发出多种,本文主要从Ti基功能陶瓷光催化材料、多种物质复合的陶瓷光催化材料和钨基活性炭基陶瓷光催化材料的性能研究和其发展应用来进行阐述。 |
| 关 键 词: | 功能陶瓷; 陶瓷基光催化材料; 光催化剂; 污水处理 |
| DOI: | 10.57237/j.mater.2022.02.003 |
1. College of Chemical Engineering, Shijiazhuang University, Shijiazhuang 050000, China
2. Hebei Agricultural Environmental Protection Monitoring Station, Shijiazhuang 050000, China
| Abstract: | With the rapid development of energy, information, environmental protection and biological science and technology, the material with a long history-ceramics, has also obtained a new research progress, namely, the development of functional ceramics. Functional ceramics play a key role in related scientific research and engineering project applications, with their unique thermal, electric, magnetic, acoustic and optical physical characteristics, chemical, biological and appropriate mechanics characteristics. Moreover, because the photocatalytic technology has the characteristics of mild reaction conditions, convenient operation and no secondary pollution, it is considered as the most promising environmental governance technology in the 21st century, that is, it can effectively solve the problems of fossil energy depletion and environmental pollution. In addition, photocatalytic technology also has the characteristics of low energy consumption, and has also become a necessary technology to develop new energy sources. If functional ceramics and photocatalytic technology are combined together, it will solve many problems in industrial production and life. A variety of materials with photocatalytic characteristics in functional ceramics have been developed. This paper mainly expounds the performance research and its development and application of Ti-based functional ceramic photocatalytic materials, multiple material composite ceramic photocatalytic materials and tungsten-based activated carbon-based ceramic photocatalytic materials. |
| Keywords: | Functional Ceramics; Ceramic-Based Photocatalytic Materials; Photocatalysts; Sewage Treatment |
| 1. | 河北省自然科学基金青年基金 (No: B2021106003) |
| 2. | 河北省高等学校青年拔尖人才计划项目 (No: BJ2021097) |
| [1] | 邹志刚. 光催化材料与太阳能转换和环境净化 [J]. 功能材料信息, 2008, 04 (4): 17-17. |
| [2] | 曲远方. 功能陶瓷材料 [M]. 化学工业出版社, 2003. |
| [3] | 于向阳, 梁文, 杜永娟, 等. 二氧化钛光催化材料的应用进展 [J]. 材料导报, 2000, 14 (002): 38-40. |
| [4] | 雷春生, 马俊杰, 宋宇星. 一种陶瓷基纳米二氧化钛膜的制备方法:, CN109174071A [P]. 2019. |
| [5] | 左娟. TiO2纳米阵列材料的制备及光电性能研究 [D]. 2005. |
| [6] | 刘荣正, 赵玉珍, 黄荣厦, 等. 三维自组装花状K2Ti6O13颗粒的水热制备及其显微结构分析 [J]. 稀有金属材料与工程, 2011, 6: 357-359. |
| [7] | 刘慧. 水热合成钛酸钾一维纳米材料的微结构表征及其光催化性能研究 [D]. 河北工业大学, 2011: 13-16. |
| [8] | Zhang X. K., Tang S. L., Yu J. Y.. A simple moltensalt method to synthesize single--crystalline potassiumtitanate nanobelts [J]. Materials Letter, 2009, 63: 887-889. |
| [9] | Xu L., Cheng L.. Environmentally friendly growthof single-crystalline K2Ti6O13, nanoribbons from KC1 flux [J]. Materials characterization, 2010, 61: 245-248. |
| [10] | 仝启杰, 齐涛, 刘玉民, 等. KOH亚熔盐法制备钛酸钾晶须和二氧化钛 [J. 工程工程学报, 2007, 7 (1): 85--89. |
| [11] | 黄风萍, 孙晶晶, 樊英鸽, 等. 纳米Nd-TiO2光催化性能的研究 [J]. 中国陶瓷, 2012, 48 (11): 22-26. |
| [12] | 蔡冬鸣, 任南琪, 李圭白. δ-MnO2吸附染料亚甲基蓝的动力学和机理 [J]. 哈尔滨工业大学学报, 2008, 40: 213-216. |
| [13] | Li J., Wang T. X., Du X. H.. Preparation of visiblelight—driven SnS2/TiO2 nanocomposite photocatalystfor the reduction of aqueous Cr (VI) [J]. Separation and purification technology, 2012, 101: 11-17. |
| [14] | Zhang Y. C., Li J., Xu H. Y.. One-step in-situsolvothermal synthesis of SnS2/TiO2 nanocompositeswith high performance in visible light—drivenphotocatalytic reduction of aqueous Cr (VI) [J]. Applied Catalysis B: Environmental, 2012, 123-124: 18-26. |
| [15] | 李靖, 张兆娟, 史小琴, 等. 功能陶瓷材料K2Ti6O13的合成和光催化性质研究 [J]. 中国陶瓷, 2014, 050 (002): 21-24. |
| [16] | 胡煜艳, 钱清华, 周雪锋, 等. 溶胶凝胶法制备六钛酸钾薄膜的光电化学性质研究 [C] // 第三届全国化学工程与生物化工年会. 0. |
| [17] | 杨术明, 寇慧芝. 水热合成法制备纳米SrTiO3光催化剂 [C] // 全国环境催化与环境材料学术会议. 2009. |
| [18] | K. Ikushina and S. Hayakwa. Solid State Electronics. 1966, 9 921. |
| [19] | 徐悦华, 古国榜, 陈小泉, 等. 复合纳米Fe2O3/TiO2的制备, 表征及光催化活性 [J]. 华南理工大学学报 (自然科学版), 2001 (11): 76-80. |
| [20] | 王丽, 赵辉, 陈永. Fe2O3/TiO2纳米管复合材料光催化降解亚甲基蓝染料废水的研究 [J]. 广州化工, 2013, 41 (10): 122-124. |
| [21] | 花中秋, 王海庆, 赵洪旺, 等. 三氧化钨陶瓷的压敏特性和机理 [J]. 硅酸盐学报, 2010 (8): 5. |
| [22] | JUAN M. JORGE L, JEAN M H, et al. Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon [J]. Applied Catalysis B: Environmental, 1998, 18 (3-4): 281-291. |
| [23] | TRYBA B,MORAWSKI A. W, INAGAKI M. A new route for preparation of TiO2 mounted activated carbon [J]. Applied Catalysis B: Environmental, 2003, 46 (1): 203-208. |
| [24] | TOYODA M, NANBU Y. KITO T, et al. Preparation and performance of anatase-loaded porous carbons for water purification [J]. Desalination, 2003, 159 (3): 273-282. |
| [25] | AMJAD H,El-Sheikh,Alan P, et al. Deposition of anatase on the surface of activated carbon [J]. Surface & Coatings Technology, 2004, 187 (2-3): 284-292. |
| [26] | EDWARD C, PATRICIA Z, SILVIA P. et al. Photocatalytic degradation of phenol using TiO2 nanocrystals supported on activated carbon [J]. Journal of Molecular Catalysis A: Chemical, 2005, 228 (1-2): 293-298. |
| [27] | 李书珍, 刘卫民, 徐佳月, 等. 以陶瓷-活性炭为载体的光催化剂降解苯酚研究 [J]. 安徽师范大学学报 (自科版), 2011 (06): 549-553. |
| [28] | 何秀兰, 郭英奎, 王春艳, 等. 多孔陶瓷负载TiO2光催化降解甲基橙溶液的研究 [J]. 人工晶体学报, 2015 (02): 000503-508. |