CO2电化学还原技术中电解池及醇胺溶液电解质的研究进展
1. 青岛科技大学, 化工学院, 山东青岛 266045
2. 青岛市即墨区科学技术局, 山东青岛 266200
3. 滨州恒一新材料有限责任公司, 山东滨州 256623
| 摘 要： | 随着工业化进程的加速和全球经济的发展，CO2排放量持续增加，导致温室气体浓度升高，气候变化问题日益严重。为了实现双碳目标下碳排放目标要求，将CO2转化为有价值的化学品对实现碳循环具有重要意义。而CO2电化学还原制备化学燃料具有操作方便、绿色等优点，是最有前途的化学燃料制备方法之一。近年来，CO2电还原反应（CO2RR）在绿色能源转换和储存方面具有广阔的前景。CO2RR是一种将电化学方法应用于CO2捕集电化学还原的技术。在CO2RR过程中，电解池的设计是至关重要的，因为它直接影响到反应的效率、选择性和稳定性。在这篇综述中首先介绍了CO2RR常用的三种类型的电解池，探讨了不同类型CO2电解池的优缺点，接着从催化剂和电解质两方面分析了影响CO2RR的主要因素。最后，介绍了一种新型替代传统的基于胺的CO2捕集方法以及研究现状，提出了未来CO2RR过程应研究方向和应用前景。 |
| 关 键 词： | 电解; CO2RR; 绿色化工; 可持续发展; 碳捕集 |
| DOI： | 10.57237/j.cse.2024.03.003 |
View:
Downloads:
收稿日期: 2024-09-03
接受日期: 2024-09-24
在线出版日期: 2024-10-26
Research Progress on Electrolytic Cell and the Electrolyte of Alcohol Amine Solution in CO2 Electrochemical Reduction Technology
1. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266045, China
2. Qingdao Jimo District Bureau of Science and Technology, Qingdao 266200, China
3. Binzhou Heng New Material Limited Liability Company, Binzhou 256623, China
| Abstract: | With the acceleration of industrialization and the development of the global economy, CO2 emissions continue to increase, leading to higher greenhouse gas concentrations and a growing climate change problem. In order to accomplish the requirements of carbon emission targets under the dual-carbon goal, the conversion of CO2 into valuable chemicals is of great significance in achieving the carbon cycle. And CO2 electrochemical reduction for the preparation of chemical fuels is one of the most promising methods for the preparation of chemical fuels with the advantages of easy operation and green color. In recent years, CO2 electrochemical reduction reaction (CO2RR) has a broad prospect for green energy conversion and storage. CO2RR is a technology that applies electrochemical methods to the electrochemical reduction of CO2 capture. In the CO2RR process, the design of the electrolytic cell is crucial because it directly affects the efficiency, selectivity and stability of the reaction. In this paper, three types of electrolytic cells commonly used for CO2RR were firstly introduced, and the advantages and disadvantages of different types of CO2 electrolytic cells were discussed, followed by analyzing the main factors affecting CO2RR in terms of both catalysts and electrolytes. Finally, a new alternative to the traditional amine-based CO2 capture method and the current research status were introduced, and the future research direction and application prospect of CO2RR process were proposed. |
| Keywords: | Electrolytic; CO2RR; Green Chemical Industry; Sustainable Development; CO2 Capture |
参考文献
| [1] | MORA C, SPIRANDELLI D, FRANKLIN E C, et al. Broad threat to humanity from cumulative climate hazards intensified by greenhouse gas emissions [J]. Nature Climate Change, 2018, 8(12): 1062-1071. |
| [2] | WU J H, HUANG Y, YE W, et al. CO2 Reduction: From the electrochemical to photochemical approach [J]. Advanced Science, 2017, 4(11): 1700194. |
| [3] | LEE J Y, TAK Y S. Electrocatalytic activity of Cu electrode in electroreduction of CO2 [J]. Electrochimica Acta, 2001, 46(19): 3015-3022. |
| [4] | LIANG S Y, ALTAF N, HUANG L, et al. Electrolytic cell design for electrochemical CO2 reduction [J]. Journal of CO2 Utilization, 2020, 35: 90-105. |
| [5] | KUHL K P, CAVE E R, ABRAM D N, et al. New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces [J]. Energy & Environmental Science, 2012, 5, 7050-7059. |
| [6] | 张瑞, 吕伟欣, 雷立旭. H型电解池中CO2电化学还原的阳极电解液问题 [J]. 电化学, 2017, 23(1): 72-79. |
| [7] | ZHANG R, LV W X, LEI L X. Problems of anodic electrolyte for electrochemical reduction of CO2 in H-type electrolytic cell [J]. Journal of Electrochemistry, 2017, 23(1): 72-79. |
| [8] | JIA Y F, LI F, FAN K, et al. Cu-based bimetallic electrocatalysts for CO2 reduction [J]. Advanced Powder Materials, 2022, 1(1): 100012. |
| [9] | 何川, 朱英明, 薛雨, 等. 纳米泡沫银用于流动池电催化还原CO2 [J]. 化学试剂, 2023, 45(8): 25-31. |
| [10] | HE C, ZHU Y M, XUE Y, et al. Silver nanofoam for flow cell electrocatalytic reduction of CO2 [J]. Chemical Reagents, 2023, 45(8): 25-31. |
| [11] | WHIPPLE D T, FINKE E C, KENIS P J A. Microfluidic reactor for the electrochemical reduction of carbon dioxide: the effect of pH [J]. Electrochemical and Solid-State Letters, 2010, 13(9): B109. |
| [12] | LEE W H, KIM Y E, YOUN M H, et al. Catholyte‐free electrocatalytic CO2 reduction to formate [J]. Angewandte Chemie International Edition, 2018, 57(23): 6883-6887. |
| [13] | BURDYNY T, SMITH W A. CO2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions [J]. Energy & Environmental Science, 2019, 12(5): 1442-1453. |
| [14] | WEEKES D M, SALVATORE D A, REYES A, et al. Electrolytic CO2 reduction in a flow cell [J]. Accounts of Chemical Research, 2018, 51(4): 910-918. |
| [15] | WAKERLEY D, LAMAISON S, WICKS J, et al. Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers [J]. Nature Energy, 2022, 7(2): 130-143. |
| [16] | MA S, SADAKIYO M, LUO R, et al. One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer [J]. Journal of Power Sources, 2016, 301: 219-228. |
| [17] | CHEN Q, WANG X Q, ZHOU Y J, et al. Electrocatalytic CO2 reduction to C2+ products in flow cells [J]. Advanced Materials, 2024, 36(5): 2303902. |
| [18] | ZHENG Y, WANG J C, YU B, et al. A review of high temperature co-electrolysis of H2O and CO2 to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology [J]. Chemical Society Reviews, 2017, 46(5): 1427-1463. |
| [19] | 王傲雪, 郭琳, 郑金玉, 等. 固体氧化物电解池材料发展现状与展望 [J]. 洁净煤技术, 2023, 29(3): 62-77. |
| [20] | WANG A X, GUO L, ZHENG J Y, et al. Solid oxide electrolytic cell materials development status and prospects [J]. Clean Coal Technology, 2023, 29(3): 62-77. |
| [21] | MOMMA A, KATO T, KAGA Y, et al. Polarization behavior of high temperature solid oxide electrolysis cells (SOEC) [J]. Journal of the Ceramic Society of Japan, 1997, 105(1221): 369-373. |
| [22] | SINGH V, MUROYAMA H, MATSUI T, et al. Feasibility of alternative electrode materials for high temperature CO2 reduction on solid oxide electrolysis cell [J]. Journal of Power Sources, 2015, 293: 642-648. |
| [23] | KIM-LOHSOONTORN P, BAE J Y. Electrochemical performance of solid oxide electrolysis cell electrodes under high-temperature coelectrolysis of steam and carbon dioxide [J]. Journal of Power Sources, 2011, 196(17): 7161-7168. |
| [24] | PARK K, LEE T H, WANG W H, et al. High-performance ruddlesden-popper perovskite oxide with in situ exsolved nanoparticles for direct CO2 electrolysis [J]. Journal of Materials Chemistry A, 2023, 11(39): 21354-21364. |
| [25] | LI Y H, HU B B, XIA C R, et al. A novel fuel electrode enabling direct CO2 electrolysis with excellent and stable cell performance [J]. Journal of Materials Chemistry A, 2017, 5(39): 20833-20842. |
| [26] | 刘红. Sr2MoFeO6-δ基用于CO2电解固体氧化物电解池电极材料的研究 [D]. 山西大学, 2023. |
| [27] | LIU H. Sr2MoFeO6-δ based electrode materials for CO2 electrolytic solid oxide cell electrolysis [D]. Shanxi university, 2023. |
| [28] | ZHAO H Y, CAO H, ZHANG Z S, et al. Modeling the potential-dpendent kinetics of CO2 electroreduction on single-nickel atom catalysts with explicit solvation [J]. ACS Catalysis, 2022, 12(18): 11380-11390. |
| [29] | LI Y F, CHEN C, CAO R, et al. Dual-atom Ag2/graphene catalyst for efficient electroreduction of CO2 to CO [J]. Applied Catalysis B: Environmental, 2020, 268: 118747. |
| [30] | WU D, CHEN W Y, WANG X W, et al. Metal-support interaction enhanced electrochemical reduction of CO2 to formate between graphene and Bi nanoparticles [J]. Journal of CO2 Utilization, 2020, 37: 353-359. |
| [31] | ZHAO Y Z, MIAO Z C, WANG F Y, et al. N-doped carbon-encapsulated nickel on reduced graphene oxide materials for efficient CO2 electroreduction to syngas with potential-independent H2/CO ratios [J]. Journal of Environmental Chemical Engineering, 2021, 9(4): 105515. |
| [32] | WANG Z Y, TIAN W S, ZHAN J Y, et al. Tunable electronic properties of graphene quantum dots guide the CO2-to-formate conversion efficiency on SnO2 nanosheet [J]. Industrial & Engineering Chemistry Research, 2023, 62(12): 4940-4946. |
| [33] | LIU W P, WANG K, GONG L, et al. Edge-located Fe-N4 sites on porous graphene-like nanosheets for boosting CO2 electroreduction [J]. Chemical Engineering Journal, 2022, 431: 134269. |
| [34] | WANG H T, XIAO Y Y, QI Y, et al. Fabrication of ZnO nanosheets self-assembled by nanoparticles for accelerated electrocatalytic reduction of CO2 to CO [J]. Fuel, 2023, 333: 126431. |
| [35] | GANG Y, PELLESSIER J, DU Z C, et al. Facile and scalable synthesis of metal- and nitrogen-doped carbon nanotubes for efficient electrochemical CO2 reduction [J]. ACS Sustainable Chemistry & Engineering, 2023, 11: 7231-7243. |
| [36] | LIU X Y, LI J Z, XUE Y, et al. Electrochemical CO2 reduction to C2+ products with Cu-oleylamine based nanoparticles synthesized by simple thermal treatment [J]. Fuel, 2023, 348: 128498. |
| [37] | WANG J G, ZHANG G Y, LIU H, et al. High-performance electrocatalytic reduction of CO2 to CO by ultrathin PdCu alloy nanosheets [J]. Separation and Purification Technology, 2023, 320: 124186. |
| [38] | MA X, WANG Q, WANG M, et al. Bi19Br3S27 nanorods for formate production from CO2 electroreduction with high efficiency and selectivity [J]. Chemical Engineering Journal, 2023, 474: 145711. |
| [39] | MARCANDALLI G, MONTEIRO M C O, GOYAL A, et al. Electrolyte effects on CO2 electrochemical reduction to CO [J]. Accounts of Chemical Research, 2022, 55(14): 1900-1911. |
| [40] | MONTEIRO M C O, DATTILA F, HAGEDOORN B, et al. Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution [J]. Nature Catalysis, 2021, 4(8): 654-662. |
| [41] | CHEN Z P, ZHANG D D, ZHANG H N, et al. Nitrogen-doped carbon nanofibers confined bismuth oxide nanocrystals boost high single-pass CO2-to-formate conversion in large area membrane electrode assembly electrolyzers [J]. Applied Surface Science, 2023, 620: 156867. |
| [42] | TAN Y C, LEE K B, SONG H, et al. Modulating local CO2 concentration as a general strategy for enhancing C-C coupling in CO2 electroreduction [J]. Joule, 2020, 4(5): 1104-1120. |
| [43] | GU J, LIU S, NI W Y, et al. Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium [J]. Nature Catalysis, 2022, 5(4): 268-276. |
| [44] | JENG E, JIAO F. Investigation of CO2 single-pass conversion in a flow electrolyzer [J]. Reaction Chemistry & Engineering, 2020, 5(9): 1768-1775. |
| [45] | HUANG J E, LI F W, OZDEN A, et al. CO2 electrolysis to multicarbon products in strong acid [J]. Science, 2021, 372(6546): 1074-1078. |
| [46] | LI J N, KORNIENKO N. Electrocatalytic carbon dioxide reduction in acid [J]. Chem Catalysis, 2022, 2(1): 29-38. |
| [47] | BONDUE C J, GRAF M, GOYAL A, et al. Suppression of hydrogen evolution in acidic electrolytes by electrochemical CO2 reduction [J]. Journal of the American Chemical Society, 2021, 143(1): 279-285. |
| [48] | FERRI M, DELAFONTAINE L, GUO S Y, et al. Steering Cu-based CO2RR electrocatalysts’ selectivity: effect of hydroxyapatite acid/base moieties in promoting formate production [J]. ACS Energy Letters, 2022, 7(7): 2304-2310. |
| [49] | KIM J H, HA T H, KIM J Y, et al. Design principles for selective and economical CO2 electrolysis in acids [J]. Applied Catalysis B: Environmental, 2023, 339: 123160. |
| [50] | CHOI W, CHOI Y J, CHOI E S, et al. Microenvironments of Cu catalysts in zero-gap membrane electrode assembly for efficient CO2 electrolysis to C2+ products [J]. Journal of Materials Chemistry A, 2022, 10(19): 10363-10372. |
| [51] | IMTEYAZ S, SURESH C M, KAUSAR T, et al. Carbon dioxide capture and its electrochemical reduction study in deep eutectic solvent (DES) via experimental and molecular simulation approaches [J]. Journal of CO2 Utilization, 2023, 68: 102349. |
| [52] | MELNIKOV S M, STEIN M. Solvation and dynamics of CO2 in aqueous alkanolamine solutions [J]. ACS Sustainable Chemistry & Engineering, 2019, 7(1): 1028-1037. |
| [53] | PICHETWANIT P, KUNGSANANT S, SUPAP T. Effects of surfactant type and structure on properties of amines for carbon dioxide capture [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 622: 126602. |
| [54] | LEE G H, LI Y G C, KIM J, et al. Electrochemical upgrade of CO2 from amine capture solution [J]. Nature Energy, 2021, 6(1): 46-53. |
| [55] | CHEN L, LI F W, ZHANG Y, et al. Electrochemical reduction of carbon dioxide in a monoethanolamine capture medium [J]. ChemSusChem, 2017, 10(20): 4109-4118. |
| [56] | PÉREZ-GALLENT E, VANKANI C, SÁNCHEZ-MARTíNEZ C, et al. Integrating CO2 capture with electrochemical conversion using amine-based capture solvents as electrolytes [J]. Industrial & Engineering Chemistry Research, 2021, 60(11): 4269-4278. |
