复合水滑石催化酯交换反应进展
1. 西安石油大学, 陕西省绿色低碳能源材料与过程工程技术研究中心, 陕西西安 710065
2. 西安石油大佳润实业有限公司, 陕西西安 710018
3. 陕西延长新能源有限责任公司, 陕西西安 710068
| 摘 要： | 生物柴油是一种绿色环保型可再生能源，是石化柴油类的首选替代品。以植物油、动物油或废食用油等为原料与醇类通过酯交换反应即可得生物柴油（脂肪酸甲酯）。文中调研了近年来以水滑石为载体负载固体碱，制备得到水滑石类（LDHs）复合氧化物，充分利用其比表面积大的特点，并将其作为催化剂用于催化制备生物柴油的文献。致力于寻找低温高效催化剂，实现生物柴油的“大丰收”。综述了水滑石的结构、不同制备方法和其在催化制备生物柴油中的作用进行了介绍，简述了不同制备方法得到的水滑石及其作为载体在催化制备生物柴油上的研究进展，发现共沉淀法和水热合成法因其制备简单，结构可控，反应条件不苛刻而深受研究者喜爱，且研究所采用的水滑石中镁铝水滑石居多，极少有研究者研究三元水滑石。除此，文中对水滑石类复合氧化物的研究前景进行了展望，应在负载型水滑石为催化剂催化制备生物柴油的研究上注重环保、绿色、节能等问题，打造并实现工业环保节能型绿色催化剂的生产。 |
| 关 键 词： | 水滑石; 催化; 生物柴油; 酯交换 |
| DOI： | 10.57237/j.cse.2023.03.002 |
View:
Downloads:
收稿日期: 2023-06-04
接受日期: 2023-07-14
在线出版日期: 2023-07-24
Progress in Transesterification Catalyzed by Composite Hydrotalcite
1. Shaanxi Provincial Green Low Carbon Energy Materials and Processes Engineering Technology Research Center, Xi'an Shiyou University, Xi'an 710065, China
2. Xi'an Petroleum University Jialun Industrial Company Limited, Xi'an 710018, China
3. Shaanxi Yanchang New Energy Company Limited, Xi'an 710068, China
| Abstract: | Biodiesel is a green and environmentally friendly renewable energy source and is the preferred alternative to petrochemical diesel. Biodiesel (fatty acid methyl esters) can be obtained by transesterification of vegetable oils, animal oils or used cooking oils with alcohols. The complex oxides of Layered Double Hydroxides (LDHs) were prepared using hydrotalcite as a carrier and loaded with solid alkali, and used as catalysts for the catalytic preparation of biodiesel. The different preparation methods of hydrotalcite are reviewed, its applications are described, the progress of research on hydrotalcite and its use as a carrier in the catalytic preparation of biodiesel is briefly described, and the research prospects of hydrotalcite-based composite oxides are also presented. |
| Keywords: | Hydrotalcite; Catalysis; Biodiesel; Transesterification |
基金
| 1. | 陕西省重点研发计划“低温快速制备生物柴油和环保型多功能油品添加剂研究” (2019GY-136) |
参考文献
| [1] | Oboh, G, Ademosun, A. O, Ogunsuyi, O. B, et al. Antioxidant, cholinesterase inhibitory, and antidepressant-like effects of hydroethanolic extract of water hyacinth (Eichhornia crassipes) [J]. Journal of Dietary Supplements, 2020, 17 (6), 750-766. |
| [2] | 陈颖, 苗双, 乔腾飞, 等. 水滑石类复合氧化物催化制备生物柴油的研究进展 [J]. 硅酸盐通报, 2016, 35 (1): 174-178+191. |
| [3] | He X W, Fang X, Chang J, et al. The genus Achyranthes: A review on traditional uses, phytochemistry, and pharmacological activities [J]. Journal of Ethnopharmacology: An Interdisciplinary Journal Devoted to Bioscientific Research on Indigenous Drugs; 2017, 203: 102-115. |
| [4] | 赵策, 曾虹燕, 黄炎, 等. 镁铁水滑石的制备及其对小球藻油脂合成生物柴油的催化性能 [J]. 燃料化学学报, 2012, 40 (3): 337-344. |
| [5] | 邓欣, 方真, 张帆, 等. 纳米水滑石的制备、特性及应用 [J]. 材料导报, 2010, 24 (S2): 35-39. |
| [6] | 邓欣, 曾虹燕, 冯波. 固定脂肪酶催化制备生物柴油条件优化 [J]. 天然产物研究与开发, 2008, 20 (1): 113. |
| [7] | Oboh, G, Olasehinde, T A, Ademosun, A O, et al. Antioxidant and cholinesterase inhibitory properties of Eichhornia crassipes (Mart.) Solms [J]. Journal of Taibah University Medical Sciences, 2019, 14 (1): 94-100. |
| [8] | Kong D, Ding Y, Liu R, et al. Eichhornia crassipes extract ameliorates cognitive dysfunction induced by lipopolysaccharide in rats [J]. Biomedicine & pharmacotherapy, 2018, 106, 721-728. |
| [9] | 邓欣, 曾虹燕, 冯震, 等. 纳米晶镁铝水滑石结晶动力学 [J]. 功能材料, 2008, (2): 341-345. |
| [10] | 杨阳. 基于MgAl-LDHs的多级结构制备及其性能 [D]. 北京化工大学, 2013. |
| [11] | 邓欣. 纳米晶镁铝水滑石超微结构可控制备及应用 [D]. 湘潭大学, 2007. |
| [12] | 何国松, 王君, 陈明强, 等. LDO催化大豆油制备生物柴油的研究 [J]. 安徽理工大学学报(自然科学版), 2011, 31 (1): 71-74. |
| [13] | 袁冰, 张新, 袁营, 等. Mg-Al类水滑石催化大豆油酯交换制备生物柴油 [J]. 应用化工, 2010, 39 (11): 1649-1652. |
| [14] | 何晗, 李山珊, 王媛. Zn-Mg-Al类水滑石催化剂催化制备生物柴油的研究 [J]. 化工设计通讯, 2019, 45 (7): 121+129. |
| [15] | 李颖欣, 黄振旭, 张红星, 等. La-Mg-Al类水滑石催化大豆油酯交换制备生物柴油 [J]. 河南化工, 2019, 36 (9): 20-23. |
| [16] | 李为民, 郑晓林, 徐春明, 等.固体碱法制备生物柴油及其性能 [J]. 化工学报, 2005, (4): 717-722. |
| [17] | 陈颖, 刘天聪, 高彦华, 等. 原位共沉淀法制备NiMg(Al)O/γ-Al2O3催化剂及其酯交换性能 [J]. 燃料化学学报, 2018, 46 (1): 59-66. |
| [18] | 丁平亮, 田志茗, 邓启刚. Ca-Mg-Al类水滑石催化大豆油甲醇酯交换制备生物柴油 [J]. 工业催化, 2011, 19 (11): 84-87. |
| [19] | Zhang L, Li E. Helical nano coiled and micro coiled carbon fibers as effective catalyst supports for electrooxidation of methanol [J]. Electrochimica Acta, 2010, 55: 6695-6702. |
| [20] | Tanaka A, Yoon S, Mochida I. Formation of fine Fe-Ni particles for the non-supported atalytic synthesis of uniform carbon nanofibers [J]. Carbon, 2004, 42: 1291-1298. |
| [21] | 黄炎, 曾虹燕, 王亚举, 等. 尿素法合成镁铁水滑石的制备机理 [J]. 硅酸盐学报, 2011, 39 (2): 365-370. |
| [22] | Benito P, Guinea I, Labajos F M. Microwave-hydrothermally aged Zn/Al hydrotalcite-like Compounds: Influence of the composition and the irradiation conditions [J]. Microporous and Mesoporous Materials, 2008, 110: 292-302. |
| [23] | 高昆, 汪朝晖, 汪效祖. 水热法制备Zn-Mg-AI花状水滑石 [J]. 功能材料, 2013, 30 (2): 126- 129. |
| [24] | 黄智, 廖其龙, 王素娟. 水热法制备棒状水滑石 [J]. 精细化工, 2008, 25 (12): 1168-1174. |
| [25] | Carlino S, Husain S w, Knowles J A. The reaction of molten phosphonic acid with a layered double hydroxide and its calcined oxides [J]. Soli. Sate Ionic, 1996, 84: 117-129. |
| [26] | 吴雁, 王豪, 钟婷. 水滑石负载钾盐催化酯交换反应合成生物柴油 [J]. 化学研究与应用, 2011, 23 (8): 1042-1047. |
| [27] | 田志茗, 常宝琪, 邓启刚. KF/锌铝水滑石的制备及其催化大豆油酯交换反应的性能 [J]. 石油化工, 2016, 45 (1): 47-51. |
| [28] | 姜绍通, 蔡静, 潘丽军, 等.生物柴油的K2CO3负载水滑石催化制备工艺 [J]. 农业机械学报, 2009, 40 (4): 102-106. |
| [29] | Carlino S, Hudson M J. Reaction of molten sebacic acid with a layered (Mg/Al) double hydroxide [J]. Journal of Materials Chemistry, 1994, 4: 99-104. |
| [30] | Panda H S, Srivastava R, Bahadur D. Intercalation of Hexacyanofe rrate (I) Ions in Layered Double Hydroxides: A novel Precursor to form ferri -antiferromagnetic exchange coupled oxides and monodi sparse nanograi n spinel ferrites [J]. The Journal of Physical Chemistry C, 2009, 113: 9560-9567. |
| [31] | Wei M, Pu M, Guo J. Intercalation of L-D opa into layered double hydroxides: enhancement of both chemical and stereochemical stabilities of a drug through host-guest interactions [J]. Chemistry of Materials, 2008, 20: 5169-5180. |
| [32] | He Q, Yin S, Sato T. Synthesis and photochemical properties of zinc-aluminum layered double hydroxide/organic UV ray absorbing molecule/silica nanocomposites [J]. Journal of Physics and Chemistry of Solids, 2004, 65: 395-402. |
| [33] | 李俊燕. 类水滑石化合物的合成及应用研究进展 [J]. 化工科技, 2015, 23 (3): 77-80. |
| [34] | Barakos N, Pasias s, Papayannakos N. Transesterification of triglycerides in high and low quality oil feeds over an HT2 hydrotaleite catalysts [J]. Bioresource Technology, 2008, 99 (11): 5037-5042. |
| [35] | Wang Y, Yan J, Gao L, et al. Mg-Al Hydrotalcite/γ-Al2O3 as Fixed-Bed Catalyst in Biodiesel Production [J]. Advanced Materials Research, 2014, 953-954: 1053-1062. |
| [36] | 靳福全, 宋全胜, 李晓红, 等. 生物柴油催化剂-镁铝复合氧化物的制备及表征 [J]. 中国油脂, 2013, 42 (1): 56-59. |
| [37] | 何晗. 复合磁性LDHs的制备及其酯交换性能 [D]. 东北石油大学, 2017. |
| [38] | 朱葛. 钙基固体碱催化微藻油脂制备生物柴油 [D]. 东北石油大学, 2015. |
| [39] | 杜昌俊, 王光华, 李文兵, 等. 磁性镁铝水滑石的制备及非均相Fenton降解甲基橙 [J]. 工业安全与环保, 2020, 46 (10): 58-61+98. |
| [40] | Ying C, Liu T, Han He. Fe3O4/ZnMg(Al)O magnetic nanoparticles for efficient biodiesel production [J]. Applied Organometallic Chemistry, 2018, 32 (5): 1-10. |
| [41] | 王豪, 吴雁, 贾艳秋, 等. 负载型镁铝水滑石催化酯交换合成生物柴油 [J]. 石油与天然气化工, 2010, 39 (5): 406-410+367. |
| [42] | 吴功德, 王晓丽, 魏伟, 等. 氟改性的镁-铝复合氧化物催化酯交换反应制备生物柴油 [J]. 石油学报(石油加工), 2011, 27 (1): 54-61. |
| [43] | Ana C, Aline A, Renkel A, et al. Thermogravimetry study of the ester interchange of sunflower oil using Mg/Al layered double hydroxides (LDH) impregnated with potassium [J]. Journal of Thermal Analysis and Calorimetry, 2017, 127 (3): 1863-1867. |
| [44] | Sun C, Qin F, Yang D, et al. Preparation of biodiesel from soybean oil catalyzed by Al-Ca hydrotalcite loaded with K2CO3 as heterogeneous solid base catalyst [J]. Fuel Processing Technology, 2014, 126: 383-391. |
| [45] | Ariel G, Teresa S, Enrique L, et al. Efficient KF loaded on MgCaAl hydrotalcite-like compounds in the transesterification of Jatropha curcas oil [J]. Journal of Alloys and Compounds, 2015, 643: S159-S164. |
| [46] | Renata N, Leonardo L, Lindoval D, et al. Study of the Use of Hydrotalcite–Hydroxyapatite as Heterogeneous Catalysts for Application in Biodiesel Using By‑Product as Raw Material [J]. Catalysis Letters, 2020, 56: 150-161. |
| [47] | Hájek M, Kutálek P, Smoláková L. Transesterification of rapeseed oil by Mg-Al mixed oxides with various Mg/Al molar ratio [J]. Chemical Engineering Journal, 2015, 263: 160-167. |
